Partition of Copper between Dissolved and Particulate Phases Using Aluminum Oxide as an Aquatic Model Phase: Effects of pH, Solids and Organic Matter
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چکیده
A adsorção de cobre sobre óxido de alumínio modificado, em meio aquoso, foi avaliada neste trabalho. A modificação do Al2O3 foi realizada através da adsorção de ácido húmico comercial à sua superfície. A adsorção do cobre foi governada por fatores tais como pH, teores de matéria orgânica (particulada e dissolvida) e concentração do material sólido. A adsorção do metal aumentou com o aumento do pH e igualmente com o aumento nos teores de matéria orgânica na fase particulada. O coeficiente de partição (Kd) do cobre diminuiu com o aumento na concentração do material sólido. Os valores de Kd foram sempre mais elevados na região de pH neutro e decresceram tanto para regiões mais baixas quanto mais elevadas de pH. Também foi observado um decréscimo na adsorção do cobre quando a concentração de matéria orgânica dissolvida foi aumentada.
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تاریخ انتشار 2000